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When you choose Register domain in Settings, you may see error DE_150:
Antispam validation failed for your domain in Accounts.
That means the sending provider rejected the domain during its anti-spam check. DNS records will not appear. You cannot finish custom domain setup until this is cleared.

What to send support

Email [email protected] with the domain you tried to add. The domain only is enough. Until support clears it:
  • Leave the default sender in place.
  • Do not keep retrying the same domain.
  • Alerts still send from [email protected].
Shopify development stores cannot register a custom domain. That is a different limit, not DE_150.
After the domain is allowed, return to Add a custom domain and finish DNS plus Check verification.